Activity

Nonylphenol ethoxylates (NPEOn) exhibit outstanding application performances, especially in stabilizing silicone oil emulsions, but have been globally banned or use-restricted for serious ecological toxicity. A homologous series of nonionic surfactants, n-dodecylbenzyloxy ethoxylates (DBEOn), are molecularly designed and synthesized as alternatives to NPEOn, where the phenolic group of NPEOn was replaced by a benzyloxy group to counteract the harmful characteristics of NPEOn, while retaining the benefits. Based on computational studies, we propose a hypothesis that has a conjugation reduction effect (CRE) of DBEOn relative to NPEOn on the surfactant structure and properties that solves the biodegradation problem while maintaining the outstanding emulsifying capacity of NPEOn. A 7-day activated sludge assessment shows that DBEO8, a representative member of DBEOn, is almost 100% biodegradable and that the poor biodegradability of NPEOn may be improved by maintaining the vital benzene ring in DBEOn molecules, because the oxygen atom of the benzyloxy group is separated from the smaller conjugation system of DBEOn. Compared to NPEO10, DBEO8 has a similar cloud point but exhibits higher benzene solubilization and considerably higher emulsion stabilities for mineral oil, biomass oil, and especially silicone oil; this outcome is ascribed to a probable random coil configuration of PEO caused by the CRE of DBEOn. Therefore, molecular design produces DBEOn with both excellent biodegradability and outstanding application performances, especially in terms of excellent emulsion stabilities of various oils, as predicted by the CRE hypothesis, thereby serving as an effective alternative to NPEOn.The strong coupling of an IR-active molecular transition with an optical mode of the cavity results in vibrational polaritons, which opens a new way to control chemical reactivity via confined electromagnetic fields of the cavity. In this study, we design a voltage-tunable open microcavity and we show the formation of multiple vibrational polaritons in methyl salicylate. A Rabi splitting and polariton anticrossing behavior is observed when the cavity mode hybridizes with the C═O stretching vibration of methyl salicylate. Furthermore, the proposed theoretical model based on coupled harmonic oscillators reveals that the absorption of uncoupled molecules must also be considered to model the experimental spectra properly and that simultaneous coupling of multiple molecular vibrations to the same cavity mode has a significant influence on the transmission spectral profile.The first enantioselective alkynylation of benzylic C-H bonds via copper-catalyzed radical relay has been established herein, which provides an easy access to structurally diverse benzylic alkynes in good yields with excellent enantioselectivities. A key step for the asymmetric copper-catalyzed radical relay process is the enantioselective capture of a benzylic radical with chiral (Box)CuII-alkynyl species. In addition, the reaction displays good functional group tolerance, broad substrate scope, and mild conditions. The enantioenriched alkynylation products can be readily transformed into highly valuable synthons, such as chiral terminal alkynes, allenes, alkenes, and carboxylic acids. More importantly, our methodology can be applied to the synthesis of bioactive molecule AMG 837.Calcium sulfate nanorods (CS-NRs) are valuable materials utilized in various applications, particularly in the medical field. In this work, the size-controlled synthesis of CS-NRs was carried out on the basis of the micelle-mediated phase separation phenomenon. A nonionic surfactant, Triton X-114, was employed for the thermoresponsive phase separation of a homogeneous solution to a surfactant-rich phase. Whereas each specific ion, Ca2+ and SO42-, was difficult to individually extract when present at concentrations less than their equilibrium concentration (solubility product constant, Ksp), the synthesized CS microrods (CS-μRs) were extracted into the surfactant-rich phase (enrichment factor = ca. 50). The presence of nitric acid increased the size of the materials up to 6707 ± 3488 nm on the long side and 87 ± 37 nm on the short side. The addition of silver nanoparticles (Ag-NPs) to the reaction mixture led to the formation of much smaller products, i.e., uniform CS-NRs whose sizes were in the range of 89 ± 15 nm (long side) and 25 ± 4 nm (short side). The size of the extracted Ag-NPs and CS-NRs decreased with an increase in added Ag-NP concentration until their microscopic observation became difficult. The factors (such as additive concentration, pH, temperature) affecting size control were evaluated.The key feature of photon echo-based spectroscopies is a selective elimination of the inhomogeneous broadening. Fast homogeneous dephasing typical for large macromolecules makes it difficult to resolve the congested spectra even if the inhomogeneous component is eliminated. We propose a novel two-dimensional spectroscopy in which a series of temporally separated probe pulses are combined with the strong narrowband control pulse. Using electromagnetically induced transparency originating from the interference between the control and probe pulses, we achieve an observation window for molecular response in narrow spectral intervals significantly smaller than the homogeneous dephasing limit.Demonstration of fundamental photophysical properties in environmentally friendly quantum dots (QDs) is essential to realize their practical use in various light harvesting applications. We accomplish here an efficient light induced resonance energy transfer in all-QD based donor-acceptor system in water, deprived of any commonly used organic dye component. ACY241 Our nanohybrid system comprises surface engineered indium phosphide/zinc sulfide (InP/ZnS) QD as the donor, and copper indium sulfide/zinc sulfide (CIS/ZnS) QD as the acceptor. The electrostatic attraction between oppositely charged QDs is vital in achieving a strong ground state complexation in the [-] InP/ZnS[+] CIS/ZnS QD nanohybrid. A nonlinear Stern-Volmer plot confirms the involvement of both static and dynamic components in the PL quenching of InP/ZnS QD by CIS/ZnS QD. Moreover, a temporal evolution of resonance energy transfer is realized in the solid state as well, which can improve the potential of such “all-green QD” based nanohybrid systems for device level studies.