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3-15.5). Condom use was significantly correlated with male gender (AOR 2.16; 95% CI 1.1-4.2) and higher educational status (AOR 4.30; 95% CI 2.1-8.8).

Our findings indicate that one in five homeless youth had sex out of marriage, and less than half did no use condom. These should be addressed by adapting education and harm reduction programs targeting this specific population in Iran.

Our findings indicate that one in five homeless youth had sex out of marriage, and less than half did no use condom. These should be addressed by adapting education and harm reduction programs targeting this specific population in Iran.Magnetic signature of the iron-bearing minerals archived in sediments is sensitive to change in environment and therefore, studied to reconstruct the signals linked with environmental processes. In the present work, we have analyzed 11 sediment cores from Vembanad lagoon, southwest coast of India, to estimate the magnetic fluctuations associated with environmental processes. Down-core variation in magnetic susceptibility and anhysteretic, isothermal and saturation isothermal remnant magnetization and S and H-ratios have been interpreted to map the degree and spatial distribution of anthropogenic pollution in and around the lagoon. Downcore variation of magnetic susceptibility of Vembanad lagoon sediments varies from 10 to 100 × 10-8 m3/ kg. The top layers of sediment samples from river mouth regions (Periyar and Muvattupuzha rivers) show higher susceptibility values and incidentally these samples are of coarse sized. The subtle variations in SIRM/χlf ratios suggest that there are magnetic grain size differences in the samples. The SIRM and χlf relation suggests that dominant magnetic grain size in sediments. The low ARM/χlf ratios suggest a relatively higher ferrimagnetic contribution and coarser magnetite grain size. Rock magnetism data reveal that the coarse magnetic grain size is affecting the pollution of Vembanad lagoon. We also analyzed downcore variability of metal concentrations such as Fe, Mn, Cu, Zn, Ni and Cr, and all these metals exhibit higher concentrations in the top layers of the cores. Our study suggests that higher values of magnetic parameters and metal concentrations are due to various anthropogenic sources.Recently, thermal-sensitive polymers absorbed much more concerns, and the goal of present work was to modify magnetic nanoparticles with N-isopropylacrylamide (NIPAM) and methyl 3,3-dimethylacrylate (DMMA) for obtaining thermal and magnetic dual-sensitive nanoparticles based on silica coated nanoscale zero valent iron and thermal-sensitive polymers (Fe@p(NIPAM-co-DMMA)). Fe@p(NIPAM-co-DMMA) nanoparticles were fabricated and possessed excellent adsorption ability for Sudan pollutants in aqueous samples. A rapid extraction and separation approach utilizing synthesized dual-sensitive nanomaterials was designed and developed before analysis by liquid chromatography (HPLC). Upon the enrichment factors as their optimal values, the established method gained wonderful linearity over the range of 0.05-500 μg L-1. The precisions of proposed method were all lower than 3.87%. The validating experiments ensured that this developed method provided with satisfied recoveries in the range of 97.4-102.6% from spiked real water samples, which affirmed that this method was a reliable monitoring tool for Sudan pollutants in water and food samples, etc.Soil pollution, caused by heavy metals, is an environmental problem that requires an urgent solution in China. Chemical passivation is a technology that uses various passivators to reduce the availability of heavy metals in soil and realize the remediation of contaminated soil. In this study, we examined the effects of fly ash (FA), alkali-fused fly ash (AFFA), swine manure biochar (SB), and modifying biochar (MB) on the leachability of Cu, Zn, Pb, and Cd via soil culture experiments. The results showed that the addition of AFFA, SB, and MB significantly reduced the extractable contents of Cu, Pb, and Cd in the soil. AFFA and MB had the best passivation effect, followed by SB and FA. The passivation effect on Pb was the best, followed by that on Cu and Cd. Elesclomol AFFA modification significantly improved the passivation effect of MB on Cu, Pb, and Cd in composite contaminated soil. With the addition of 3% MB, the Pb, Cu, and Cd extracted by TCLP decreased by 95.7, 74.1, and 59.1%, respectively. Correlation analysis, Fourier transform infrared spectrometry, scanning electron microscopy, and energy-dispersive X-ray spectroscopy showed that the passivation mechanism is mainly due to an increase in the soil pH, silicate content, and cohesiveness. The soil culture experiments in this study proved that MB is a low-cost and highly efficient organic-inorganic composite passivator for multi-metal contaminated soils.Organosilicon compounds have numerous applications in consumer products. After entering the environment most of them are resistant against microbial degradation and they persist in the environment. Accordingly, they are ubiquitously present in the environment. Therefore, better environmentally degradable organosilicon compounds are urgently needed. A systematic investigation of environmental degradability of organosilicon compounds allows to derive some general design principles, which in turn would enable chemists to reduce or better avoid environmental persistence of organosilicon compounds in the environment. Therefore, in this study, all organosilicon substances registered in the European Chemicals Agency (ECHA) database were evaluated for their environmental biodegradability. Results of own experiments with different organosilicon substances were added to extend the data basis. A dataset was generated. An assessment of all data was done and invalid data were excluded. The remaining 182 substances were grouped regarding their structure to derive general rules for the environmental biodegradability of organosilicon compounds. Non-biodegradable at all were for example cyclic, linear and branched siloxanes. Groups like ethers, esters, oximes, amines, and amides were prone to hydrolysis, which can result in readily biodegradable intermediates if they do not contain silicon functional groups anymore. This knowledge could be used for the design of better degradable organosilicon compounds as non-degradable substances should be avoided if they enter the environment after their usage.