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Hesselberg Vincent posted an update 2 weeks, 1 day ago
The overall results reveal that EDTA-EMR is a promising adsorbent ascribed by its low cost, good recyclability and excellent adsorption capacity.Microplastics pollution has emerged as one of the top-ranked global environmental issues, receiving worldwide attention in recent years. However, knowledge about the detrimental effects of microplastics on human health is still limited. In real-world settings, the physicochemical characteristics of microplastics were modified by environmental and biological transformation, largely changing their ultimate toxicity. Nonetheless, the toxicity change related to transformation of microplastics has not been considered in most published studies thus far. In the current study, we investigated the cytotoxicity of transformed polystyrene microplastics in hepatocytes. Emricasan Our results revealed that 500 nm polystyrene microplastics, which were chemically transformed by simulated gastricfluid, exacerbated their adverse effects on SMMC-7721 cells at 20 μg/mL for 24 h treatment, including morphological alteration, membrane damage and increased cell apoptosis via oxidative stress. This exacerbated cytotoxicity could be at least partially explained by the degradation, changed surface charge and altered surface chemistry of these polystyrene microplastics after transformation. In conclusion, our study demonstrates that the hepatic cytotoxicity of polystyrene microplastics is enhanced after transformation.Fe-C micro-electrolysis system has been widely used in filters, or as an advanced treatment process in some water treatment plants to treat various wastewater. In this study, Fe-C micro-electrolysis process was enhanced by an economical and environmentally friendly method, applied magnetic field. Batch kinetic experiments and scanning electron micrographs demonstrated a more effective micro-electrolysis and more severely corroded on the surface of Fe-C after applying a magnetic field at pH 3.0. An applied magnetic field reduced the charge-transfer resistance and increased the current density in micro-electrolysis system and Fe-C became more prone to electrochemical corrosion. Corrosion products were proved to be Fe2+, Fe3O4, and C-O, moreover, the formation of them were also increased in the presence of a magnetic field. Base on that, some influential factors like magnetic field flux intensity, Fe-C particle size, pH, Fe-C dosage and its reusability were investigated in this paper. Since Fe2+ release was accelerated in micro-electrolysis system by an applied magnetic field, combination of various advanced oxidation processes were designed to explore the application effectiveness of the system. The degradation rate of target contaminant was significantly improved in the presence of a magnetic field, suggesting it could be a reliable method for wastewater treatment.The release of asbestos fibers in old buildings, during demolition, or remodeling is associated with severe public health risks to building occupants and workers. In Korea, asbestos was used in several building materials during the 20th century. Although the use of asbestos is currently banned, its widespread earlier use and the current government initiatives to revitalize dilapidated areas make it essential to accurately evaluate the location and status of asbestos-containing materials (ACMs). This study surveyed buildings in an area of deteriorated dwellings targeted for renewal and determined the status and distribution of ACMs in that area. Asbestos distribution maps were generated and asbestos characteristics were analyzed. In addition, the risk posed by the identified ACMs was assessed using four international methods (the Korean Ministry of Environment, US Environmental Protection Agency, American Society for Testing and Materials, and UK Health and Safety Executive methods), and the results were compared. Notable differences between the assessment results were identified and were found to reflect the specific characteristics of buildings in the study area. These findings suggest ACM risk assessments should be specifically tailored to the regions in which they are applied, thereby improving ACM management and promoting both worker and occupant health.Defects are significant for graphitic carbon nitride (g-C3N4, CN) in photocatalytic applications. Defective CN not only accelerate charge separation but also extend spectral response. Engineering carbon or nitrogen defects in CN has been achieved by variety of strategies, but it is still a long-term interest to develop a simple and controllable route for engineering defects in CN. Herein, we present tuning the nitrogen defects in CN by either changing the heating rate or prolonging the pyrolysis time during polymerization melamine sulfate. It was found that either lower heating rate or longer pyrolysis time lead to the formation of more N vacancies and suspended terminal amino. As a result, an optimal photocatalytic H2 yield rate (λ > 420 nm) of 905 μmol g-1 h-1 was reached, which was 2 times higher than that of CN prepared with a heating rate of 1 °C/min and pyrolysis at 600 °C for 4 h.Constructing metal-oxo-bridge coordination as electron transfer bridge is benefit for the catalysis acceleration towards water pollutants treatment. In this work, regulable Cu-O-C configuration was constructed through tunable ratio of copper aluminum oxide (CuAlxOy) and porous g-C3N4 (p-CN), employed as electron transfer bridge for Cu(II)/Cu(I) redox behavior modulation to realize sufficient peroxymonosulfate (PMS) activation. A series of characterization demonstrated that the composites presents porous structure for p-CN contribution, and the oxygen content plays crucial role in Cu-O-C bonds fabrication. The proper ratio of CuAlxOy and p-CN is conducive to create an oxygen-rich environment, resulting in high dispersed copper atoms connect with oxygen in p-CN matrix. As a result, 21 CuAl@p-CN possesses appropriate Cu-O-C configuration, has favorable electron transfer environment for rapid redox behavior of Cu(II)/Cu(I), leading to excellent PMS activation for mirco-polluted veterinary antibiotics elimination.