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The lasing-mode number was positively correlated with the length of the perovskite nanorods. Therefore, the prepared perovskite nanorod array with random sizes can be transformed into a quaternary cryptographic key array following encoding rules based on the lasing-mode number. Superior lasing stability was observed for the all-inorganic perovskite under continuous excitation, demonstrating the high reliability of this system.Harsh conditions are inevitable for long-term use of self-healing polymers. However, the majority of reported self-healing materials cannot remain stable under harsh conditions due to the presence of vulnerable dynamic crosslinking sites. Herein, a universal self-healing poly(dimethylsiloxane) (PDMS) polymer is reported. In our design, the PDMS polymer chains are crosslinked predominantly through physical entanglements. Owing to the invulnerable nature of the entanglement junctions and high mobility of polymer chains, the as-synthesized polymer exhibits autonomous self-healing capabilities not only under ambient conditions but also in a variety of harsh environments, including aqueous solutions, organic solvents, and extreme conditions (strong acid/alkali, redox agents, freezing temperature). Moreover, this polymer can be easily integrated with a eutectic gallium-indium (EGaIn) alloy to achieve layer-by-layer self-healing electronic skin sensors, which realize the combination of excellent electrical conductivity, long-term sensing stability, and universal self-healing capability.Adenosine receptors (ARs) have been involved in neurodegenerative diseases such as Alzheimer disease, where oxidative stress contributes to neurodegeneration and cell death. Therefore, there is increasing interest in developing antioxidative strategies to avoid or reduce neurodegeneration. We have previously described that different beer extracts modulate ARs and protect glioma and neuroblastoma cells from oxidative stress. The present work aimed to analyze the possible protective effect of hops (Humulus lupulus L.), a major component of beer, and xanthohumol on cell death elicited by oxidative stress and their modulation of ARs in rat C6 glioma and human SH-SY5Y neuroblastoma cells. Different extraction methods were employed in two hops varieties (Nugget and Columbus). Cell viability was determined by the XTT method in cells exposed to these hops extracts and xanthohumol. ARs were analyzed by radioligand binding and real-time PCR assays. Hops extract reverted the cell death observed under oxidative stress and modulated adenosine A1 and A2 receptors in both cell types. Xanthohumol was unable to revert the effect of oxidative stress in cell viability but it also modulated ARs similarly to hops. Therefore, healthy effects of beer described previously could be due, at least in part, to their content of hops and the modulation of ARs.Polyoxometalates (POMs) are a class of discrete molecular inorganic metal-oxide clusters with reversible multielectron redox capability. Taking advantage of their redox properties, POMs are thus expected to be directly involved in the lithium-sulfur batteries (Li-S, LSBs) system as a bidirectional molecular catalyst. Herein, we design a three-dimensional porous structure of reduced graphene-carbon nanotube skeleton supported POM catalyst as a high-conductive and high-stability host material. Based on various spectroscopic techniques and in situ electrochemical studies together with computational methods, the catalytic mechanism of POM clusters in Li-S battery was systematically clarified at the molecular level. The constructed POM-based sulfur cathode delivers a reversible capacity 1110 mAh g-1 at 1.0 C and cycling stability up to 1000 cycles at 3.0 C. Furthermore, Li-S pouch/beaker batteries with a POM-based cathode were successfully demonstrated. Trometamol This work provides essential inputs to promote molecular catalyst design and its application in LSBs.Much attention has been paid to understanding the individual effects of surface chemistry or topography on cell behavior. However, the synergistic influence of both surface chemistry and surface topography on differentiation of human mesenchymal stem cells (hMSCs) should also be addressed. Here, gold nanoparticles were immobilized in an increasing number density manner to achieve a surface topography gradient; a thin film rich in amine (-NH2) or methyl (-CH3) chemical groups was plasma-polymerized to adjust the surface chemistry of the outermost layer (ppAA and ppOD, respectively). hMSCs were cultured on these model substrates with defined surface chemistry and surface topography gradient. The morphology and focal adhesion (FA) formation of hMSCs were first examined. hMSC differentiation was then co-induced in osteogenic and adipogenic medium, as well as in the presence of extracellular-signal-regulated kinase1/2 (ERK1/2) and RhoA/Rho-associated protein kinase (ROCK) inhibitors. The results show that the introduction of nanotopography could enhance FA formation and osteogenesis but inhibited adipogenesis on both ppAA and ppOD surfaces, indicating that the surface chemistry could regulate hMSC differentiation, in a surface topography-dependent manner. RhoA/ROCK and ERK1/2 signaling pathways may participate in this process. This study demonstrated that surface chemistry and surface topography can jointly affect cell morphology, FA formation, and thus osteogenic/adipogenic differentiation of hMSCs. These findings highlight the importance of the synergistic effect of different material properties on regulation of cell response, which has important implications in designing functional biomaterials.Multifunctional superamphiphobic cotton fabrics are in high demand. However, preparation of such fabrics is often difficult or complicated. Herein, a novel superamphiphobic fabric is constructed by a simple one-pot method with an in situ growth process. Under suitable alkaline conditions, dopamine (DA) can be oxidized to benzoquinone. Meanwhile, 3-aminopropyltriethoxysilane (APTES), 1H,1H,2H,2H-perfluorodecyltriethoxysilane (FAS-17) molecules undergo the hydrolysis reaction and bond together. Besides, benzoquinone can react with APTES by Schiff base and hollow nanoclusters can be finally obtained because of the steric hindrance effect of benzene ring and long alkyl chain. Such nanoclusters are formed on the surface of fabric, which endows the fabric with extreme liquid repellence. The effects of pH value and DA concentration on the surface morphology and lyophobic properties of the fabric are systematically studied. The water and pump oil contact angles of the superamphiphobic fabric obtained under the optimal reaction conditions can reach 160 and 151°, respectively.