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  • Kerr Didriksen posted an update 2 days, 12 hours ago

    Polymer nanocomposites (PNC) have attracted enormous scientific and technological interest due to their applications in energy storage, electronics, biosensing, drug delivery, cosmetics and packaging industry. Nanomaterials (platelet, fibers, spheroids, whiskers, rods) dispersed in different types of polymer matrices constitute such PNC. The degree of dispersion of the inorganic nanomaterials in the polymer matrix, as well as the structured arrangement of the nanomaterials, are some of the key factors influencing the overall performance of the nanocomposite. To this end, the surface functionalization of the nanomaterials determines its state of dispersion within the polymer matrix. For energy storage and electronics, these nanomaterials are usually chosen for their dielectric properties for enhancing the performance of device applications. Although several reviews on surface modification of nanomaterials have been reported, a review on the surface functionalization of nanomaterials as it pertains to polymer dielectrics is currently lacking. This review summarizes the recent developments in the surface modification of important metal oxide dielectric nanomaterials including Silicon dioxide (SiO2), titanium dioxide (TiO2), barium titanate (BaTiO3), and aluminum oxide (Al2O3) by chemical agents such as silanes, phosphonic acids, and dopamine. We report the impact of chemical modification of the nanomaterial on the dielectric performance (dielectric constant, breakdown strength, and energy density) of the nanocomposite. Aside from bringing novice and experts up to speed in the area of polymer dielectric nanocomposites, this review will serve as an intellectual resource in the selection of appropriate chemical agents for functionalizing nanomaterials for use in specific polymer matrix so as to potentially tune the final performance of nanocomposite.Quantitative image analysis is an important tool in understanding cell fate processes through the study of cell morphological changes in terms of size, shape, number, and orientation. In this context, this work explores systematically the main challenges involved in the quantitative analysis of fluorescence microscopy images and also proposes a new protocol while comparing its outcome with the widely used Image J analysis. It is important to mention that fluorescence microscopy is by far most widely used in biocompatibility analysis (observing cell fate changes) of implantable biomaterials. In this study, we employed two different image analyses toolsets (i) the conventionally employed ImageJ software, and (ii) a recently developed automated digital image analyses framework, called ImageMKS. While ImageJ offers a powerful toolset for image analyses, it requires sophisticated user expertise to design and iteratively refine the analyses workflow. This workflow primarily comprises a sequence of image transformations that typically involve de-noising and labelling of features. On the other hand, ImageMKS automates the image analyses protocol to a large extent, and thereby mitigates the influence of the user bias on the final results. This aspect is addressed using a case study of C2C12 mouse myoblast cells grown on Poly(vinyldiene difluoride) based polymeric substrates in the presence of an external electric field. In particular, we used a number of fluorescence microscopy images of murine myoblasts (muscle precursor cells) grown on Poly (vinylidene difluoride), PVDF based nanobiocomposites under the influence of electric field. It was observed that when compared with the findings obtained from ImageJ, ImageMKS workflows consistently produced more reliable results that correlated better with the prior studies. Sodium palmitate price Furthermore, the MKS workflows required much less user time, because of their automation.We investigated the effect of an electric treatment on the wettability of aqueous solution on carbon nanotubes (CNT) and ion transport behaviors in superhydrophobic porous carbon nanotube sponges (CNTS). This electric activation treatment where an electric voltage was applied across highly porous CNT sponge induced an electrowetting effect. This effect significantly reduced interfacial tensions between CNT sidewalls and aqueous liquids. Meanwhile, polar functional groups were also introduced on CNTs. Both electrowetting effect and polar functional groups greatly improved the wettability of aqueous solutions on CNT sidewalls. After the electric treatment, we observed a dramatic increase in the overall rate of ion flow across porous CNT sponges. The formation of solution channels during the electric treatment is responsible for the enhanced ionic transport in porous CNT sponges. The overall rate of ion flow increased with the increases in electric treatment time and voltage. The crucial role of electric treatment parameters in the ion transport provides a new strategy for precisely controlling the ion transport across CNT sponges by tuning electric treatment time or voltage. Importantly, the good wettability of aqueous solution on CNT sidewalls greatly increased the effective surface area of CNT sponges and thus significantly improved the performance of CNTS-based supercapacitors after the electric treatment.Lead-halide perovskites have demonstrated astonishing increases in power conversion efficiency in photovoltaics over the last decade. The most efficient perovskite devices now outperform industry-standard multi-crystalline silicon solar cells, despite the fact that perovskites are typically grown at low temperature using simple solution-based methods. However, the toxicity of lead and its ready solubility in water are concerns for widespread implementation. These challenges, alongside the many successes of the perovskites, have motivated significant efforts across multiple disciplines to find lead-free and stable alternatives which could mimic the ability of the perovskites to achieve high performance with low temperature, facile fabrication methods. This Review discusses the computational and experimental approaches that have been taken to discover lead-free perovskite-inspired materials, and the recent successes and challenges in synthesizing these compounds. The atomistic origins of the extraordinary performance exhibited by lead-halide perovskites in photovoltaic devices is discussed, alongside the key challenges in engineering such high-performance in alternative, next-generation materials.